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First TBSI-75


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Need to eliminate reversion in thick natural rubber parts and improve steel cord adhesion? First® TBSI‑75 replaces TBBS+PVI with a single accelerator. No reversion, water‑stable, and significantly boosts heat‑aged adhesion to brass‑plated steel. Ideal for heavy truck tires, earthmover treads, and conveyor belts.
Product Categories: Accelerator Sulfonamide Accelerator
  • Chemical composition: N-tert-Butyl-bis(2-benzothiazolyl) sulfenimide
  • Complex carrier: EPDM/SBR
  • Characteristics: Natural rubber and synthetic rubber's post-curing, eco-friendly accelerators—particularly suited for carbon black compounds with high alkalinity—offer excellent scorch resistance, ensuring safe handling even at elevated temperatures. They also promote faster vulcanization while maintaining outstanding resistance to reduction. These accelerators can effectively replace the TBBS + PVI system in large-scale, thick natural rubber products. With their high molecular weight, elevated melting point, and superior thermal stability, they remain stable even when exposed to water. Additionally, they enhance the heat resistance and durability of steel cord-to-rubber adhesion, making them an ideal choice for demanding applications.

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  • Product Description
  • Pain point you may have faced
    You produce large, thick natural rubber articles – heavy truck tires, giant earthmover treads, or thick rubber pads. Conventional accelerators like TBBS need PVI to achieve acceptable scorch safety, but even then, reversion during long cure cycles kills physical properties. Worse, in steel‑cord reinforced applications (e.g., tire belts, bead fillers), the adhesion between rubber and brass‑plated steel degrades rapidly under heat and humidity. You have also noticed that some accelerators lose effectiveness when the compound gets damp or during prolonged storage.

    Why TBSI‑75 is different
    First® TBSI‑75 is a post‑curing, eco‑friendly accelerator specifically designed for natural and synthetic rubbers – particularly effective in high‑alkalinity carbon black compounds. It offers excellent scorch resistance, keeping you safe even at elevated processing temperatures, while delivering fast vulcanization and outstanding reduction resistance (no reversion). Unlike TBBS, TBSI‑75 can effectively replace the TBBS + PVI system in large, thick natural rubber products – simplifying your formulation without sacrificing safety.

    What makes it unique

    High molecular weight & high melting point – less volatility, cleaner factory air.

    Superior thermal stability – remains stable even when the rubber compound is exposed to water or high humidity.

    Enhances steel cord adhesion – significantly improves the heat resistance and durability of the bond between rubber and brass‑plated steel cords, critical for tire belts, bead wires, and hose reinforcements.

    What you gain

    One accelerator replaces two – no need for separate PVI, reduce inventory and dosing errors.

    No reversion – thick parts maintain tensile strength, tear resistance, and modulus.

    Water‑stable – compound stays consistent even in humid environments or after rain exposure on the mill.

    Longer lasting adhesion – steel cord bond survives higher service temperatures and longer aging.

    Real‑world result
    A steel‑cord conveyor belt manufacturer was using TBBS + PVI in their thick (25 mm) belt cover compound. They experienced reversion spots and occasional adhesion failure after heat aging. After switching to First® TBSI‑75 at the same total phr (1.2 phr, without PVI), scorch safety actually improved, cure time remained similar, and heat‑aged adhesion values (measured after 7 days at 100°C) increased by 40%. The belt passed ISO 15236 requirements without any formulation rework.

    Typical specifications

    Appearance: light gray to off‑white granules

    Active ingredient: N‑tert‑butyl‑bis(2‑benzothiazole) sulfenimide (approx. 75%)

    Carrier: EPDM/SBR

    Recommended dosage: 0.8–1.5 phr (as primary accelerator, no PVI needed for most recipes)

    Packaging: 25 kg carton with inner PE liner

    Storage: 12 months in unopened packaging, cool and dry (tolerant to brief moisture exposure)

    Samples and technical data sheets are available. No hard selling — just for your evaluation.

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